metal-to-ligand charge transfer

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• Charge-transfer complex — A charge transfer complex (CT complex) or electron donor acceptor complex is an association of two or more molecules, or of different parts of one very large molecule, in which a fraction of electronic charge is transferred between the molecular… …   Wikipedia

• Charge transfer complex — A charge transfer complex (or CT complex, electron donor acceptor complex) is a chemical association of two or more molecules, or of different parts of one very large molecule, in which the attraction between the molecules (or parts) is created… …   Wikipedia

• Metal L-edge — Figure 1: L3 and L2 edges of [CuCl4]2 …   Wikipedia

• Intervalence charge transfer — In spectrometry, the intervalence charge transfer, sometimes called the IVCT or even IT, is an absorption in the electromagnetic spectrum that is characteristic of bi and polymetallic coordination complexes that are mixed valence. According to… …   Wikipedia

• Transition metal — The term transition metal (sometimes also called a transition element) has two possible meanings: The IUPAC definition[1] states that a transition metal is an element whose atom has an incomplete d sub shell, or which can give rise to cations… …   Wikipedia

• Metal K-edge — is the excitation of a 1s electron to valence bound states localized on the metal. The K edge can be divided into the pre edge region, which comprises the pre edge and rising edge transitions and the near edge region, which comprises the intense… …   Wikipedia

• Metal aquo complex — Metal aquo complexes are coordination compounds containing metal ions with only water as a ligand. These complexes are the predominant species in aqueous solutions of many metal salts, such as metal nitrates, sulfates, and perchlorates. They have …   Wikipedia

• Metal-organic framework — Metal Organic Frameworks are crystalline compounds consisting of metal ions or clusters coordinated to often rigid organic molecules to form one , two , or three dimensional structures that can be porous. In some cases, the pores are stable to… …   Wikipedia

• Non-innocent ligand — In chemistry, a (redox) non innocent ligand is a ligand in a metal complex where the oxidation state is unclear. Typically, complexes containing non innocent ligands are redox active at mild potentials. The concept assumes that redox reactions in …   Wikipedia

• Oxo ligand — In coordination chemistry, an oxo ligand is an oxygen atom bound only to one or more metal centers. These ligands can exist as terminal or (most commonly) as bridging atom (Fig. 1). Oxo ligands stabilize high oxidation states of a metal.[1] Fig.… …   Wikipedia

• Inner sphere electron transfer — Inner sphere or bonded electron transfer[1] proceeds via a covalent linkage between the two redox partners, the oxidant and the reductant. In Inner Sphere (IS) electron transfer (ET), a ligand bridges the two metal redox centers during the… …   Wikipedia